Full Article: PDF
Scientific Object Identifier: http://s-o-i.org/1.1/TAS-02-82-60
DOI: https://dx.doi.org/10.15863/TAS.2020.02.82.60
Language: English
Citation: Safaev, U. A., & Karabaeva, Z. T. (2020). Scrunity of polymerization and co-polymerization of some bromine-containing monomers vinylseries. ISJ Theoretical & Applied Science, 02 (82), 368-375. Soi: http://s-o-i.org/1.1/TAS-02-82-60 Doi: https://dx.doi.org/10.15863/TAS.2020.02.82.60 |
Pages: 368-375
Published: 28.02.2020
Abstract: The article extends the results of kinetic studies of some halogen-containing vinyl monomers. Analyzing the behavior of bromine-containing monomers in binary systems with amino compounds revealed the occurrence of spontaneous polymerization of some monomers with an active bromine atom when they interact with tertiary amines. This is clarified by the activity of the bromine atom, which manifests itself in the dependence of the structure of the bromine-containing component.The goal of the work was to study the influence of functional groups on the reactivity of a double bond in halogen-containing vinyl monomers.When researching the kinetics of the copolymerization of bromine-containing monomers with acrylonitrile, into the bargain,studying the mutual influence of the bromine atom and double bond in the monomers under study, it was shown that the presence of a reactive bromine atom greatly influences the copolymerization process and the properties of the resulting copolymers, which makes it possible to more purposefully, moreover to implement the synthesis of a number of macromolecular compounds, as well as their further chemical transformation.
Key words: polymerization, copolymerization, bromine-containing monomer, spontaneous polymerization, reaction kinetics, polymerization rate.
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