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www.T-Science.org       p-ISSN 2308-4944 (print)       e-ISSN 2409-0085 (online)
SOI: 1.1/TAS         DOI: 10.15863/TAS

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ISJ Theoretical & Applied Science 06(62) 2018

Philadelphia, USA

* Scientific Article * Impact Factor 6.630


Magerramov A, Ahmedov I, Gurbanova M, Huseyinov E

SYNTHESIS OF A NEW CAMPHOR-DERIVED CHIRAL ORGANIC PHOSPHORIC ACID CATALYST AND ITS APPLICATION IN THE HANTZSCH REACTION.

Full Article: PDF

Scientific Object Identifier: http://s-o-i.org/1.1/TAS-06-62-11

DOI: https://dx.doi.org/10.15863/TAS.2018.06.62.11

Language: English

Citation: Magerramov A, Ahmedov I, Gurbanova M, Huseyinov E (2018) SYNTHESIS OF A NEW CAMPHOR-DERIVED CHIRAL ORGANIC PHOSPHORIC ACID CATALYST AND ITS APPLICATION IN THE HANTZSCH REACTION. ISJ Theoretical & Applied Science, 06 (62): 48-51. Soi: http://s-o-i.org/1.1/TAS-06-62-11 Doi: https://dx.doi.org/10.15863/TAS.2018.06.62.11

Pages: 48-51

Published: 30.06.2018

Abstract: A new chiral, camphor-derived organic phosphoric acid catalyst, 2-endo-3-endo-dimethylbornane-2,3-diyl phosphate, was synthesized and was succesfully used as organocatalyst in the synthesis of optical active 3-ethyl 5-methyl 6-methyl-4-(4-nitrophenyl)-2-(trifluoromethyl)-1,4-dihydropyridine-3,5-dicarboxylate (3), and methyl 2,2,7-trimethyl-5-(4-nitrophenyl)-4-oxo-5,8-dihydro-4H-[1,3]dioxino[4,5-b]pyridine-6-carboxylate (4).

Key words: Hantzsch reaction, dihydropyridine, chiral organocatalysts.


 

 

 

 

 

 

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