ISJ Theoretical & Applied Science 05(49) 2017

ISPC Technology and progress, Philadelphia, USA

Khogjayev HG

HALOGENATION OF OLEFINS INVOLVING EPOXIDES AND HALIDES OF AMIDES OF SULFONIC ACIDS-A PATHWAY TO THE SYNTHESIS OF HALOIDS.

Full Article: PDF

Scientific Object Identifier: http://s-o-i.org/1.1/TAS-05-49-9

DOI: https://dx.doi.org/10.15863/TAS.2017.05.49.9

Language: Russian

Citation: Khogjayev HG (2017) HALOGENATION OF OLEFINS INVOLVING EPOXIDES AND HALIDES OF AMIDES OF SULFONIC ACIDS-A PATHWAY TO THE SYNTHESIS OF HALOIDS. ISJ Theoretical & Applied Science, 05 (49): 48-52. Soi: http://s-o-i.org/1.1/TAS-05-49-9 Doi: https://dx.doi.org/10.15863/TAS.2017.05.49.9

Pages: 48-52

Published: 30.05.2017

Abstract: Methods of halogenation of cyclohexen involving glycidol were developed. During the reaction two isomers were formed: 1-(2-halogencyclohexoloxy)-2-bromine-3-hydroxypropane(I) and 1-(2- halogencyclohexoloxy)-2-hydroxy-3-brominepropane(II). It was found that the compound (I) forms an ethoxy compound, but the (II) compound doesn’t. During the reaction of ethoxy compund with hydrogen halide two products were derived that differed by the position of the halogen atom. When the mixture of cyclohexene and glycidol is chlorinated a similar course of reaction is observed which proves that the nature of halogen does not affect the joint halogenation reaction. In connection with the preparation of hard-to-divisible compounds, we have developed a method for the production of chloro-ethers by the reaction of the interaction of chloroamide of sulfonic acids with olefins in the presence of alcohols.

Key words: haloids, glycidol, cyclohexen, epoxy compounds, chloramine-B, bromohydrine.