ISJ Theoretical & Applied Science 04(72) 2019

Philadelphia, USA

Mahmudova, A. A., Mammadova, G. H., Babayev, S. S., Mammadov, S. A., & Zeynalova, L. F.

Study of reactivity of hydroxyl group in 1-aryloxynonanol-2.

Full Article: PDF

Scientific Object Identifier: http://s-o-i.org/1.1/TAS-04-72-47

DOI: https://dx.doi.org/10.15863/TAS.2019.04.72.47

Language: English

Citation: Mahmudova, A. A., Mammadova, G. H., Babayev, S. S., Mammadov, S. A., & Zeynalova, L. F. (2019). Study of reactivity of hydroxyl group in 1-aryloxynonanol-2. ISJ Theoretical & Applied Science, 04 (72), 371-376. Soi: http://s-o-i.org/1.1/TAS-04-72-47 Doi: https://dx.doi.org/10.15863/TAS.2019.04.72.47

Pages: 371-376

Published: 30.04.2019

Abstract: The reactivity of hydroxyl group in 1-aryloxynonanol-2 which was obtained by the interaction of heptyloxirane with substituted phenols in the presence of sodium metal was studied. The content of aromatic radical intensifies protonization of hydroxyl group. As a result in the reaction of 1-aryloxynonanol-2 with ?-chloro ethers (chloro methoxyethyl) yields of ethers with dimethylaniline make 75-85%. The reaction of obtaining amides and thioamides with isocyanates and isothiocyanates also goes easily. The position of a substituent in phenol fragment has a little effect on the reactivity of hydroxyl group.

Key words: aryloxynonanol-2, ?-chloro ethers, urethane, arylisocyanates, arylisothicyanates, antimicrobial property.